As someone who have both, I can say Arjuna will definitely help you more than Amakusa. Arjuna has better Buster crits and NP1 damage, while also being pretty good at farming, and if you have powerful supporters like Merlin, Oberon or Koyanskaya, you can easily dish out some crazy damage. He's basically like a cheat code. Post buffs Amakusa is also extremely good, but he's more like niche tanky DPS that you'll most likely bring in a difficult stall battles, or if the enemy is spamming buffs every few turns. I guess you can also use him as a semi-support, but idk if anyone even use him that way. Overall, both are amazing units, so pick whoever you like the most